• This is the second in a series of two danburites obtained from AJS Gems. This is a brief study, and a more formal and much more detailed study will be presented at a later date. The following is based on microscopic imagery obtained through darkroom conditions and illuminating as such.

    There were some different artifacts found compared to the last one, but at the same time there were some others of like kind, and some artifacts that are just different and unique to this second specimen. Then again at a microscopic level, no two stones are going to be identical but they will have like characteristics.

    This particular specimen is a Portuguese oval that is very well proportioned. There are no visible windows or extinction. They’re not ideal proportions, but the crown has been compensated enough with the shape of the pavilion to compensate for much of that. So all and all as far as colored gem stones go, this is nearly as good as you could expect on the cutting.

    This particular specimen is by vendor documentation 9.96 carats. It is by any standard a collectors size stone. It is completely flawless with a standard 10x loupe. Under the microscope, while there are artifacts to be observed, it is a relatively clean stone microscopically though not flawless.

    This study was a bit more difficult as I was using a better video card that actually hindered things in some instances as compared to the last one. Some artifacts you can’t detect so readily simply because they are as colorless as the body.

    I initially described this stone as being D ? in color meaning a split between D and E if you compared it to a diamond. Having seen an E colored diamond, this stone has less color than that. It will disappear in a glass of water. So if you’re looking for a diamond substitute or just want something not so common and a complete freak of nature on so many levels, this is a stone you might want to acquire as part of your collection or to mount in a piece of jewelry.

    Keep in mind that larger sized stones are more difficult to examine with a microscope as the one being used here, and these things have a very high dispersion. To put it in perspective to the mineral and gemology buffs who might be reading this, with the right lighting and camera angle, it looks like a colorless sphene. However, there is no such thing that I know of, but for descriptive purposes, it can appear that way.

    It is also interesting to note that there is one small difference between danburites and sphenes (also known as titanite geologically). Had the conditions been a bit different and the absence of boron, this could have easily turned into a sphene as the same chemical elements are there. Danburites are like sphenes in that they have a higher disperson than a diamond, and there are very few stones that can say that. The presence of rutile inclusions has been observed in both specimens.

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    This is the stone face up under 15x. We can see the silver tone. Like with the first specimen, there is a very mirror like tone from the pavilion with the cotton backing. This may appear more blue due to the presence of either phosphors or a krypton/xenon blend of gases in the LED.

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    This is about 17x. We can begin to see some very small solid phased inclusions from this level of magnification.

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    This is under 24x. We can see some rutile like fields here. These aren’t smudges as this was polished with the same clean jewelers cloth that a particular vendor of diamonds sells.

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    This is the same view as above. However, if you notice, there is this obvious rhombohedral shaped inclusion that is solid and single phase. We see no evidence of growth rings at all. However, this inclusion and others like it suggest some metamorphic event. That will be explored in greater depth at a later time.

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    This is at about 30x, and is only 1 quadrant of the stone. That should give you an idea as to how large this stone is.

    Take note of 2 things in a highlighted version of this image as above:

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    The rectangular area outlines what appears to be a possible rhombohedral/prismatic and colorless solid. Near that, we see something fuzzy that is hexagonal in shape within the same vicinity. It looks like a gas type inclusion, but my suspiscion is that this is merely artifact based on other imagery to be illustrated later in this text.

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    This is the same 30x view, and the stone was simply repositioned to an adjacent quadrant. We can see the rutile, and we can see what appears to be a colorless pyramidal terminating end of a rhombohedral crystal. That would be consistent with danburite or basic silicates. However, silicate in this host is more readily seen as the previous specimen imagery illustrates.

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    This is an area of rutile inclusions at 50x.

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    These are some mica appearing inclusions that are solid and single phase at 220x. Based on this, it is suggestive of some form of hydrothermal formation. That is not the same as a stone that has been produced using hydrothermal synthesis. This is suggestive of a geological occurrence, and a clue as to the supposed origin.

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    This is the stone at 25x with exposure to UV-A.

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    This is the same as the above except with UV-A off. We can observe a slight green and mostly inert fluorescence at best here and there. Some of that may or may not be artifact, but there are no signs of growth rings.

    The yellow elliptical shape is there to highlight what appears to be at this view a gas inclusion. However, that’s not the case. It is not a nuance, but a legitimate artifact within the host.

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    This appeared to be a gas inclusion from the pavilion, however we can see a cluster of close in proximity. Aside from some faint rutile inclusions, this is observed at 61x. These are merely closely knit solids, and due to lighting conditions and the diffusion of light from them, they can appear to be gas like as one might see in other gemstones from other localities.

    The same tests were done with the pavilion view with UV-A at 22x.

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    This is with UV-A on.

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    This is with UV-A off. We can see an inert green, and some indications of solid artifacts that appear to be in tact.

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    From the pavilion view at 40x, we can see solid inclusions that are in a more or less laminar pattern. That would be consistent with what is perhaps the c-axis of the crystal before it was cut, and consistent with the growth patterns of danburites.

    Amongst other imagery, this may be more for aesthetics than any other value, but attempts were made to capture the dispersion of the stone and certain patterns projected onto the paper background that this specimen was placed over.

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    Note the patterns of the shadows overlapping, and note the dispersion from the stone. There are 4 LED light sources within the microscope head. Though a bit out of focus, you can observe a great deal of dispersion of light and some rainbow like gradients displaying on a plain white sheet of paper.

    2009-07-16-03741

    This is an alternate view of the same image above.

    The formal study will comprise artifacts of both specimens, and further evidence and explanations will be presented there.

    -joe

  • Introduction:

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    Original imagery as taken by AJS Gems.

    This is part 1 of 3 in a series of a study of corundum specimens. This document entails a study using micrographs and various non-destructive study and examination with instrumentation available. This document details observations as noted, along with supporting imagery.

    The first specimen examined was a purple sapphire disclosed as being heat treated in a manner that virtually all sapphires are treated in (with some rare exceptions). The specimen was also disclosed as originating from Madagascar.

    Objectives:

    The following objectives were defined in this study.

    1. Is the stone examined in fact natural or synthetic?
    2. Is there any evidence of additional of different thermal enhancements other than those disclosed at the time of sale?
    3. Is there any evidence to support the origin of this stone?

    Background:

    There is very little information that is conclusive as to purple sapphires that are published and readily available. What information that is available online collectively is conflicting or inconclusive as to properties of synthetics with respect to UV fluorescence, chemical composition, etc.

    As with any synthetic corundum, strong fluorescence of certain colors denotes a synthetic. This particular specimen appears to glow pink to pinkish red under exposure to UV-A using a hand held UV lamp. Many sources cite this as being a tell tale sign of a synthetic. However, the GIA published an article in Gems and Gemology citing a moderate to strong fluorescence in purple sapphires from Pakistan. The material used in the study was said to be in the range of light purple to shades overlapping amethyst and plum colors. It also cites origins of like material to be from Tanzania, Ceylon, etc.

    Based on that source, the test for UV fluorescence is inconclusive as to the stone being natural or synthetic, and it doesn’t conclude the origin to be Madagascar or anywhere else. So as such, we have another possibility of origin.

    Much is published citing vanadium as being the coloring agent for purple sapphire, and other sources suggest this to be what is responsible for making some sapphires change colors. Other sources suggest the purple being the mixture of a sapphire and a ruby. In such a case, titanium with chromium would blend in the aluminum oxide matrix, and accept iron as a toning agent to produce a certain color. In either case, it would be a rare combination of elements to combine as such to produce this material. Regardless, many sources say that where rubies and sapphires are found, purple sapphires are found as well. This would imply (at least) that is possible for this stone to be from Madagascar since it is a known source for both rubies and sapphires.

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  • Over the past several months, due to various enhancements amongst various colored stones, the demand for untreated or unenhanced stones has increased. If a stone is in fact unenhanced, there can be no question as to what treatment has or hasn’t been applied to it. However, pending on what type of gem we’re talking about, these are more or less common-and priced accordingly.

    I came across some piece of information that said if you wish to tell if an aquamarine is heated or not, a gemologist with a standard loupe can tell. If you’re very lucky, and/or you’re looking at a rough specimen, that may be one thing. The only stones that I’ve seen that have been said to have been unheated looked more like green beryl than they did aquamarine. In case you’re wondering, green beryl is the same chemical composition as an emerald, except they are much cleaner and significantly less saturated in color. A lot of times, aquamarine rough comes out of the ground in a unique shade of green.

    Well, do you want a green aquamarine or do you want a blue aquamarine? The overwhelming majority of buyers want blue, and not green. So if it’s blue it’s heated. Is it?

    Consider the following 2 images:

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    20090111_190746 Read more…

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  • The following is to illustrate certain artifacts with opals and to provide some general and technical information about them. There are more varieties than you typically see in most retailers, and there are a lot of synthetics out there. There are also a lot of doublets and triplets on the market.

    While either a synthetic, triplet or doublet might be attractive and affordable to many, they are not naturally. What’s worse is that most people don’t know the difference, and some entities will sell certain items without disclosing and explaining what these things mean. That’s the bad part. The other bad news is, if you want something natural, and good, anymore you’re going to pay for it if it’s of quality and pending the size and specifics.

    Natural opals anymore have become quite expensive pending on the exact type. Yes, there is more than one type of opal. Pending what kind of opal it is, and it’s particulars, you will pay more or less for it. They were quite popular during the 1980’s as they have a myriad of colors which fit into the outrageous trends of the time. So suddenly they became popular, and they were relatively more affordable than they are now. The demand increased, the mines in Australia are simply not producing as much material. The strength in the Aussie dollar against the US dollar forced a doubling in the prices alone, so something had to give. That something was the quality and the rise of synthetics with the exception of certain higher end jewelers.

    I’ve always been a fan of the more unusual stones, and things you don’t ordinarily see. The illustration below is a natural opal showing no evidence of enhancements that was purchased from AJS Gems. This is a 0.97 carat trillion cabochon magnified 45x.

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  • The following is a brief and exploratory study of a 3.87 carat yellow tourmaline I purchased from www.ajsgems.com Gems some time ago. The methodologies involved are non destructive and include microscopic testing as well as some imagery coupled with long wave UV testing. I thought I would share at least some of the more interesting pictures I obtained, and a few artifacts that threw me for a loop-but in a good way.

    Yellow tourmaline is more or less a collectors stone, and anything particularly of gem quality of a carat or better is considered a collector size stone. The rough is often incredibly included, so there is little yield as a result. This study is meant to be a brief version of a more complete study of like kind that may or may not be published later on. These are simply the highlights and some things that are of interest.
    I made the mistake of wiping the stone with a lotion containing tissue after rinsing it, hence why I could never get a good face up shot. It’s all dirty as a result, but it is remarkably clean for a yellow tourmaline-especially of this size. The polariscope without the polars crossed shows a slight pleochroism, but under various lighting conditions I have noticed a more obvious pleochroism within the stone. I can also tell you that it is uniaxial negative with a chronoscope, which is consistent with yellow tourmaline by pretty much any account I could find.
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  • The following is a brief study using microscopic imagery regarding a pink tourmaline specimen from AJS Gems that was acquired some time ago. This was originally documented as a study of 3 tourmalines; most of which were acquired from AJS Gems. There will be a 4th study conducted in a like manner at a later time to include another specimen. A more detailed study or addendum to this might be published at a later date perhaps.

    This following images depict a 4.16 carat pink tourmaline, and it was disclosed as being from Nigeria and unheated. The very strong and intense pink colors have been said to originate from Nigeria, and don’t need heating as a result. There is an absence of orange undertones, but in certain lighting conditions, you can see more or less of it. It doesn’t have the orange color shift property that a Brazilian specimen from acquired from AJS Gems as well. I found all sorts of interesting artifacts in this particular tourmaline.

    These images are uncompressed and unedited with the exception of green elliptical shapes to draw your attention to certain things that I thought were of interest. Other than the interpolation for resizing with the microscope software, no revisions have been made. Note that the blue background is actually a white napkin, so the colors for some reason are off a bit. I don’t have any software to color correct things anymore since my OS upgrade-otherwise I’d illustrate both the original and color corrected versions. Unless otherwise specified, the only light source being used is the LED light source from the microscope used. No ambient light was present at the time these images were obtained; a darkroom type condition was used for the study of this particular specimen.

    Under a polariscope, and 20x magnification, there is evidence of a pink to orange pleochroism without the filters crossed over the diffused light source. With the polarizing filters crossed, there is evidence of double refraction consistent with tourmalines. I could not obtain an accurate optic sign and character with my chonoscope. Then again, I suspect this is due to the scope itself as my particular one is a pain to work with. I did see some hint of yellow towards the outside perimeter of where the optic character would be, thus suggesting it’s negative. Tourmalines for the most part are uni-axial negative with some exceptions.
    Additionally, when I placed the stone directly over the bottom plate, I did see a lot lighter color and one portion of some growth rings. They seemed to be more or less linear with minimal delineation before an arc. They didn’t appear to be completely curvilinear like you would find in a synthetic stone. This region was between the bottom quarter and third of the stone in which these were observed with diffused polarized light. There was evidence of pink color zoning much like you might see in a Ceylon sapphire of some color, and the zoning appeared to be consistent with some other smaller specimens I examined under a loupe under incandescent lighting. This zoning was isolated, and the stone in it’s entirety appeared to be anisotropic through and through with crossed and uncrossed polars. I wasn’t able to obtain imagery of this zoning due to limitations of ergonomic design of the equipment being used, but I have found it in another tourmaline specimen. That imagery will be published at a later date.

    Note the solid crystal inclusions highlited in green.
    This was originally observed with some solid inclusions near the top left region of this image adjacent to each other at 30x that illustrate some misshapen inclusions. However, further examination of this image shows what looks like a terminal end on 2 crystals side by side. These appear to be in tact. Note the reflection off the faces of the one terminal end. These 2 are circled in green. This misshapen part could suggest thermal enhancement or some other thermal event that occurred naturally. However, the terminal ends suggest an absence of thermal enhancements.
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  • Whoa…thats a peridot! :-)

    Dear Arnold, Matt, Rung, et abla..

    My mother got her peridot today. I thought maybe the flight scheduling with FedEx might have delayed things, or the weather. There were no delays. Its ironic how you in Bangkok can get a package through the same courier as a network out of Atlanta, and even though Atlanta is just a short distance, I can bet on a package from AJS Gems arriving faster than some network. So I got to give you guys recognition for shipping merchandise out in a very timely manner.

    Where do I start on this peridot? Mom was hoping it was a little darker, but I figure when its mounted in a ring, it very well may. There are certain tell tale signs of that. However, she did compare this to her beloved Arizona peridot in a ring she bought from a local jeweler. This specimen is not your typical pale colored stuff. The Arizona stuff tends to be a paler yellowish green. Its not quite as saturated as this material. I am not going to say the Arizona stuff is bad, but its less per carat as a result. A few years back when we tried to find this same material from this locality, nobody ever heard of it.
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  • As the birthstone for March (and associated with the 19th wedding anniversary) aquamarine is one of the Oval shape Aquamarinemost often maligned gemstones of the age. Most people, if theyve seen the stone at all, have been presented with specimens that are so washed out they retain nothing of the proper color associated with the aquamarine gemstone.

    Fine quality aquamarine comes from nature in colors from blue-green to a light sky blue: nothing colorless or washed out - these stones are supposed to look blue… Whats unique about aquamarine, is that the majority of these seawater blue stones are flawless: the perfect centerpiece for a fine piece of aquamarine jewelry

    As the second most well known beryl (after emerald), aquamarine was once credited with protecting against poison, sailors carried and slept with the incredible colored gemstones to ensure a safe voyage. Today a gift of fine quality aquamarine jewelry can symbolize safety and security: especially in long term relationships. Some say it may even re-ignite love in a marriage.

    So what piece of aquamarine jewelry to choose?

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  • If your birthday falls in the month of October or the astrological sign of Libra, you have the good fortune to have one of the most beautiful of gemstones associated with your birth. Available in shades from the palest pink to the scorchingly hottest pinks and everything in between: this gemstone has become a favorite of women everywhere. And with all the cuts to choose from - trillion, round, emerald, oval, square, pear and cushion - this fabulously colored stone is certainly ready to play its part at the center of any piece of pink tourmaline jewelry that you might choose.

    Pink Tourmaline - 6.79 ct. Unheated OvalPink tourmaline is said to be a powerful influence on love and friendship, spirituality and creativity as well as granting wisdom and enhancing willpower. The prices and value of pink tourmaline vary tremendously, depending on the size and quality of the gemstone, and youll soon learn that no two stones are alike. When it comes to the gift of pink tourmaline jewelry, there are an abundance of wonderful styles to choose from…

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  • Long before Prince Charles gave Lady Diana that stunning sapphire engagement ring there were pieces of fine colored gemstone jewelry made to showcase this most precious of gems. September babies, those born under the zodiac sign Taurus (or those celebrating a 45th wedding anniversary) have long laid claim to blue sapphire as their own, prompting jewelry designers to create many distinctive styles that feature the full range of sapphire hues.

    Still theres something about that blue that remains unmatched…

    Todays sapphire earring styles run the gamut from casual to dazzling and drop dead gorgeous. Sapphire rings are an especially popular choice (even for engagement rings) since the gemstone is both beautiful and durable. Sapphire at the neckline continues to be popular, but the quality of the gemstone is king here: accent stones too must be a match to the quality of the center stone.

    One of the most intriguing types of sapphire is the so called star sapphire. This type of sapphire is blessed with the rare characteristic of asterism caused by tiny quantities of rutile inclusions. These inclusions reflect light back in the form of a six-rayed star that looks as though it glides across the face of the gemstone. The effect is both striking and offers a special significance to the gift of these gemstones - shes your shining star.

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